The measuring principle is infrared single-line absorption spectroscopy, which is
based on the fact that each gas has distinct absorption lines at specific
wavelengths. The measuring principle is illustrated in Figure 1-1. The laser
wavelength is scanned across a chosen absorption line of the gas to be
measured. The absorption line is carefully selected to avoid cross interference
from other (background) gases.

The detected light intensity varies as a function of the laser wavelength
due to absorption of the targeted gas molecules in the optical
path between transmitter and receiver. In order to increase sensitivity the
wavelength modulation technique is employed: the laser wavelength is slightly
modulated while scanning the absorption line. The detector signal is spectrally
decomposed into frequency components at harmonics of the laser modulation
frequency. The second harmonics of the signal is used to measure the
concentration of the absorbing gas. The line amplitude and line width are both
extracted from the second harmonics line shape, which makes the measured
concentration insensitive to line shape variations (line broadening effect) caused
by background gases.
NOTE: The AO2000-LS25 measures the concentration of only the FREE
molecules of the specific gas, thus not being sensitive to the molecules bound with
some other molecules into complexes and to the molecules attached to or
dissolved in particles and droplets. Care should be taken when comparing the
measurements with the results from other measurement techniques.
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